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A2B'B''O6型双钙钛矿氧化物的研究进展
作者:裴志鹏     夏伟仁 朱信华 
单位:(固体微结构物理国家重点实验室 南京大学物理学院 南京 210093) 
关键词:双钙钛矿氧化物 制备方法 铁电 铁磁 多铁性 微结构表征 
分类号:TQ174
出版年,卷(期):页码:2019,47(4):0-0
DOI:
摘要:

 双钙钛矿氧化物具有A2B?B?O6结构通式,通常碱土金属离子占据A位,过渡金属或者镧系金属离子占据B位。由于B位离子(B?和B?)的组合方式多样化,使得双钙钛矿结构氧化物拥有多种晶体畸变类型,呈现出丰富的强关联物理现象 (如庞磁电阻效应、电子相分离、电荷/轨道有序等),这为人们研究电子强关联物理机制提供了一个良好的研究体系。综述了近年来双钙钛矿氧化物的研究进展:首先介绍晶体结构特征、制备方法及微结构表征技术,重点评述了其铁电、铁磁及多铁性方面的研究进展;其次讨论了它们在自旋电子学、铁电光伏及固体燃料电池领域的应用前景;最后指出了目前双钙钛矿氧化物研究需要重点关注的一些问题。

 Double perovskite oxides have a general structural formula of A2B?B?O6, where alkaline earth metal cations sit at A-sites and B-sites are occupied by cations of transition metal elements or lanthanide metal elements. The double perovskite oxides have many types of crystal structural distortions due to the complex combinations of B-site cations, showing the abundant strong correlation phenomena such as colossal magnetoresistance effect, metal-insulator transition, electronic phase separation, and charge/orbital ordering. This provides a challenging aspect for investigating the physical mechanisms of correlation phenomena. Recent work on double perovskite oxides were reviewed. The crystal structural features, synthesized methods and microstructural characterized techniques of double perovskite oxides were introduced. Research progress of ferroelectric, ferromagnetic, and multiferroic properties of double perovskite oxides were represented. Their potential applications in the fields of spintronics, ferroelectric photovoltaics, and solid fuel cells were also discussed. In addition, the main issues for the current research of double perovskite oxides were also given.

基金项目:
国家自然科学基金项目(11674161);江苏省自然科学基金项目(BK20181250)。
作者简介:
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